Nitrogen compounds are one of the several materials in the
wastewaters and effluents that have harmful effects in water resources. In
different experiences , Ion Exchange (IE) with Zeolites were used for
removal of Ammonia-nitrogen. The aim of this research was studying the
application of Semnan’s Zeolite for removal of Ammonium in both Batch
and Continous systems .
The Zeolite Clinoptilolite was supplied by Semnan area mines . The
Zeolite was ground and sieves based on U.S. standard mesh number
20 , 30 , 40 and then conditioned by Ammonium Sulfate and Sodium
Chloride solutions respectively .
The test results on conditioned samples in Batch system was showed
that average Ion Exchange capacity for particles with 20 , 30 and 40
mesh were between 6.65 - 16 mg NH4+ / g Zeolite weight .
Forthermore its selectivity for other cations obtained the ranking of K , NH4 ,
Na , Ca , Mg respectivly . In Continous system , total cation exchange
and till breakthrough point capacity obtain 16.31 - 19.5 and 7.61 - 11.23
mg NH4+ / g Zeolite weight . The resultes indicated that high level of
regeneration (95 - 98%) may be achieved with solution of NaCl .
At present time, the most wastewater treatment plant in our country
designed for removal of organic matter and Ammonium remain in
effluent , and the use of Ion Exchange with Clinoptilolite can be led to
economical remove of NH4 + from effluent .
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